Effect of biodiesel on fuel injection systems

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Introduction

This page reproduces information found in the Joint Fuel Injection Equipment Manufacturers Statement, a study by the following manufacturers into the effect of biodiesel (aka FAME) and associated impurities on diesel fuel injection systems.

  • Delphi Diesel Systems
  • Stanadyne Automotive Corporation
  • Denso Corporation
  • Robert Bosch GmbH

Biodiesel and impurities

Fuel Characteristic Effect Failure Mode
Fatty Acid Methyl Esters (general) Causes some elastomers including Nitrile rubbers to soften, swell, or harden and crack Fuel leakage
Free Methanol in FAME Corrodes aluminium & zinc
Low flash point
Corrosion of fuel injection equipment
FAME process chemicals Potassium and sodium compounds
Solid particles
Blocked Nozzles
Dissolved water in FAME Reversion of FAME to fatty acid Filter Plugging
Free water in mixtures Corrosion
Sustains bacteria
Increases the electrical conductivity of fuel
Corrosion of fuel injection equipment
Sludging
Free glycerine Corrodes non ferrous metals
Soaks cellulose filters
Sediments on moving parts
Lacquering
Filter clogging

Injector Coking
Mono- & di-glyceride Similar to glycerine
Free Fatty Acid Provides an electrolyte and hastens the corrosion of zinc
Salts of organic acids
Organic compounds formed
Corrosion of fuel injection equipment
Filter plugging
Sediments on parts
Higher modulus of elasticity Increases injection pressure Potential of reduced service life
High viscosity at low temperature Generates excessive heat locally in rotary distributor pumps
Higher stressed components
Pump seizures
Early life failures
Poor nozzle spray atomisation
Solid impurities Potential lubricity problems Reduced service life

Ageing products

Fuel Characteristic Effect Failure Mode
Corrosive acids (formic & acetic) Corrodes all metallic parts
may form simple cell
Corrosion of fuel injection equipment
Higher molecular organic acids Similar to fatty acid
Polymerisation products Deposits especially from fuel mixes Filter plugging
Lacquering formation in hot areas

Considerations for homebrew biodiesel

The document highlights the need to produce a good quality fuel product to run in your vehicle.

Many biodiesel homebrewers will have seen reddish drop-out in their fuel when mixed with mineral fuels, as highlighted in the Polymerisation products section above. If mixing is required, it is advisable to do this outside of the vehicles tank, and settled for at least 24 hours prior to fuelling.