MSDS - Potassium hydroxide

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Potassium Hydroxide material data safety sheet. Reproduced with kind permission of the Department of Chemistry, Oxford University.

Last updated January 18, 2007

Common synonyms	Caustic potash Lye
Formula	KOH
Properties	Form: White semi-transparent flaky solid. Stability: Stable, but hygroscopic. Absorbs carbon dioxide from the air. Melting point: 360°C Water solubility: high (dissolution is very exothermic). Specific gravity: 2.04
Principal hazards	Contact with the eyes can cause serious long-term damage. The solid and its solutions are corrosive. A significant amount of heat is released when potassium hydroxide dissolves in water; this may be sufficient to crack thin glassware if the solution is not stirred when dissolving the solid.
Safe handling	Always wear safety glasses. Do not allow solid or solution to come into contact with your skin. When preparing solutions swirl the liquid gently to prevent "hot spots" developing.
Emergency	Eye contact: Immediately flush the eye with plenty of water. Continue for at least ten minutes and call for immediate medical help. Skin contact: Wash off with plenty of water. Remove any contaminated clothing. If the skin reddens or appears damaged, call for medical aid. If swallowed: Drink plenty of water and call for immediate medical help.
Disposal	Small amounts of dilute potassium hydroxide can be flushed down a sink with a large quantity of water, unless local rules prohibit this. Larger amounts should be neutralised before disposal.
Protective equipment	ALWAYS wear safety glasses when handling potassium hydroxide or its solutions. For many chemicals safety glasses are needed because when the chemical gets in the eye it causes irritation; by contrast, potassium hydroxide can cause serious damage. If you need gloves, neoprene, nitrile or natural rubber are suitable for handling solutions at concentrations of up to 70%.
Further information	More extensive safety data

Bio-rich-time-poor 21:07, 25 June 2011 (BST)