I had a quick flick through the MSDS and to me it doesn't sound that bad considering we play with methanol day in and day out. This sounds certainly seems far safer from a toxicity point of view in that the effects are both short term and reversible.
I'm wondering if it's really worth bothering with. I'm quite happy to suffer a slight loss in performance (not that it's very noticeable in a Disco) given the economics of making and running bio.
Despite running like a snail on Valium most of the time, the Disco is definitely sluggish wen cold and considerably so in cold weather. Once up to running temperature, which can take some time, it seems to run OK in even in a very cold ambient. If you are only doing short journeys, could you be seeing the same issue?
What would concern me is running it in the Golf, given the temperatures at which the fuel system appears to run. Presumably mixing it with bio will reduce it's auto-ignition temperature but as parts of the fuel system run at nearly 70°C at tick over, under a heavy load for prolonged periods the quoted auto-ignition temperature could be approached.