Biodiesel

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Biodiesel (chemical name fatty acid methyl esters), has very similar combustion properties to mineral diesel, making it a suitable substitute for mineral diesel in road vehicles.

Biodiesel should not be confused with vegetable oil, or blends of vegetable oil with solvents such as petrol.

Contents


Advantages

Biodiesel presents several advantages over pure vegetable oil as a road fuel:

  • significantly reduced viscosity; good for systems with weak mechanical injection pumps (EG Lucas, which can shear its driveshaft with vegetable oil)
  • lower melt point; can be used in winter
  • can be safely cold-started; no piston ring gumming and resulting loss of compression

How it is made

Biodiesel is made from vegetable oil using a chemical process to split the vegetable oil molecules. This is done in a biodiesel processor.

Vegetable oil in molecular form looks similar to a garden hand fork with three prongs, some of which are bent and different lengths, and a very short, heavy handle. Imagine a large number of these in a bin. If you jiggle them all up (heating) and then let them settle (cooling) it's inevitable that when you go to pour them out of the bin, some will be tangled together (which is similar to how piston ring gumming with a cold engine occurs).

Converting vegetable oil into biodiesel is like breaking all the prongs off the forks and throwing the handles (glycerol) away. You can shake all the individual prongs up as much as you like but they won't tangle together as easily, which is why biodiesel doesn't gum up piston rings like vegetable oil.

Blends

B5, B30 and B100 refer to blends of biodiesel with mineral diesel. B30 is 30% biodiesel, 70% mineral diesel. Some vehicles run happily on B100, whereas for others, the manufacturer may specify a maximum blend. Ambient temperature is also an influencing factor, as Biodiesel can "wax up" before mineral diesel at lower temperatures.

Quality standards

The European standard for biodiesel is EN14214, although in the UK commercial producers are not legally required to produce fuel meeting this standard. Buyer beware.

In the US this standard is ASTM D 6751.

Chemical process

Methanol is deprotonated using NaOH, to make it a stronger nucleophile:-

Trans1.gif

The methoxide attacks the electrophillic carbonyl carbon atom of the triglyceride via an Sn2 mechanism, forming a tetrahedral intermediate.

This is an equilibrium reaction so an excess of methanol is used to drive the equilibrium to the right, favouring the formation of product.


The tetrahedral intermediate collapses and expels the alkoxy anion of the diglyceride, leaving the methyl ester product:-

Trans2.gif

Finally, the diglyceride anion is protonated, regenerating the catalyst:-

Trans3.gif

The regenerated catalyst is now able to react with another methanol molecule, beginning another cycle.

The transesterification continues until all three fatty acid groups have been converted to methyl esters, leaving just the glycerol backbone as the main by-product.

(special thanks to Twenty4Seven for the images and explanatory chemistry)

See also