Thanks for doing that, Jules. It unfortunately blows my unpopulated pin 1 theory out of the water!
Here's a photo of my plug opened out ...

The four coloured wires, I think, are just the standard for a USB connection.
The other 8 wires are pin ... 2 (Bus +), 4&5 commoned (ground), 6 (CAN high), 7 (K line), 10 (Bus -), 14 (Can low), 15 (L line) and 16 (+12v)
There are two chips on one side and one on the reverse, although that one may just be a collection of resistors or transistors (it's got that sort of look about it).
I'm tempted to try de-soldering the wires to pins 2, 6, 10 and 14 to replicate your cable as closely as possible ... haven't really got anything to loose.
I'll post up the results tomorrow, but I think it's a long shot. Otherwise I think I'll splash out on a cable that claims to be win 8 and VCDS compatible and has a single LED in a similar position to yours. Were there any other distinguishing features on the cable which might help identify it?
Thanks for your continued and invaluable tech support!