Difference between revisions of "Blending vegetable oil with solvents"

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<metadesc>Blended Biofuels Diesel</metadesc>
 
<metadesc>Blended Biofuels Diesel</metadesc>
  
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Blended Biofuels Diesel (BBD), ''Vegetable oil blended diesel fuel'' (VOBDF), “Waste oil blended diesel fuel” (WOBDF) is a substitute for petroleum-based diesel fuel. BBD is produced by blending oils with solvents. The purpose of making a biofuels blend diesel is to thin the resulting blended fuel to near the viscosity of diesel fuel, to improve the blend’s burn characteristics, and reduce its gel-point. The resulting solution should be a uniform solution without precipitates.
+
Vegetable oil may be blended with solvents as a substitute for petroleum-based diesel fuel. A blend thins the oil to near the viscosity of diesel fuel to improve the burn characteristics and reduce the gel-point. The resulting should be a uniform solution without precipitates.
  
 
[[File:Toluol+WVO.1.2.jpg‎|thumb|right|WVO before solvent is added to it (source: Jeffrey S. Brooks)]]
 
[[File:Toluol+WVO.1.2.jpg‎|thumb|right|WVO before solvent is added to it (source: Jeffrey S. Brooks)]]
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[[File:Toluol+WVO.3.JPEG‎|thumb|right|WVO just after solvent is added to it (source: Jeffrey S. Brooks)]]
 
[[File:Toluol+WVO.3.JPEG‎|thumb|right|WVO just after solvent is added to it (source: Jeffrey S. Brooks)]]
 
[[File:Toluol+WVO.4.JPEG‎|thumb|right|WVO five minutes after solvent added to it.  The solution has become uniform (source: Jeffrey S. Brooks)]]
 
[[File:Toluol+WVO.4.JPEG‎|thumb|right|WVO five minutes after solvent added to it.  The solution has become uniform (source: Jeffrey S. Brooks)]]
−
 
  
 
__TOC__
 
__TOC__
  
−
==Overcoming myths==
+
==Safety of light solvents in a diesel engine==
−
Blending waste oils with light solvents, such as gasoline (petrol) or kerosene (paraffin) requires overcoming some myths that persist in the diesel industry. It is commonly believed that one should never put gasoline (petrol) or kerosene (paraffin) into a diesel engine; however, the British owner’s manuals for Mercedes-Benz [http://i1084.photobucket.com/albums/j411/jhananda/Bio-fuels/Ownersmanual83Mercedes.jpg ref], Mercedes 190D 2.5 Manual (British) [http://i1084.photobucket.com/albums/j411/jhananda/Bio-fuels/Ownersmanual1991Mercedes190D.jpg ref], BMW Owner's Manual (British) [http://i1084.photobucket.com/albums/j411/jhananda/Bio-fuels/Ownersmanual80sBMW.jpg ref] and Volkswagen Pickup owner’s manual (British)equipped with diesel engines from 1978 through 1991 stated "UP TO 30% GASOLINE" (or kerosene in the USA) may be added for cold weather starting.
 
  
−
The Haynes Techbook (10330) Diesel Engine Repair Manual states, "If gasoline is accidentally pumped into the fuel tank, it won't hurt the fuel system or the engine…Gasoline in small amounts – 0 to 30% - isn't noticeable. At higher ratios, the engine will make a knocking noise, which will get louder as the amount of gasoline goes up..."
+
Blending waste oils with solvents such as gasoline (petrol) or kerosene (paraffin) requires overcoming some myths that persist in the diesel industry. It is commonly believed that they will cause damage to a diesel engine; however, the British owner’s manuals for Mercedes-Benz [http://i1084.photobucket.com/albums/j411/jhananda/Bio-fuels/Ownersmanual83Mercedes.jpg ref], Mercedes 190D 2.5 Manual [http://i1084.photobucket.com/albums/j411/jhananda/Bio-fuels/Ownersmanual1991Mercedes190D.jpg ref], BMW Owner's Manual (British) [http://i1084.photobucket.com/albums/j411/jhananda/Bio-fuels/Ownersmanual80sBMW.jpg ref] and Volkswagen Pickup owner’s manual (equipped with diesel engines from 1978 through 1991) state "UP TO 30% GASOLINE" (or kerosene in the USA) may be added for cold weather starting.
  
−
Recent research at the University of Wisconsin shows gasoline can be used as a “spark plug” when blended with diesel fuel improves economy and emissions [http://www.gizmag.com/diesel-spark-plug-gasoline/12484/ ref]
+
The Haynes Techbook (10330) Diesel Engine Repair Manual also states, "If gasoline is accidentally pumped into the fuel tank, it won't hurt the fuel system or the engine… Gasoline in small amounts – 0 to 30% - isn't noticeable. At higher ratios, the engine will make a knocking noise, which will get louder as the amount of gasoline goes up..."
  
−
We can conclude that adding gasoline (petrol) or kerosene (paraffin) below 30% in a fuel blend for a diesel engine will not cause mechanical failure.  Thus blending these solvents with waste oils should reduce the potential harm a light hyrdo-carbon, such as gasoline (petrol) or kerosene (paraffin) can cause.
+
Research at the University of Wisconsin shows gasoline can be used as a "spark plug" when blended with diesel fuel improves economy and emissions [http://www.gizmag.com/diesel-spark-plug-gasoline/12484/ ref]
  
 +
Below 30% in diesel fuel system will not cause mechanical failure, though with higher solvent ratios, hot fuel system components may potentially cause a vapour-lock that prevents the fuel from being pumped.
  
 
==Cosolvent blending==
 
==Cosolvent blending==
−
“Vegetable oils are an attractive renewable source for alternative diesel fuels. However, the relatively high kinematic viscosity of vegetable oils must be reduced to make them more compatible with conventional compression-ignition engines and fuel systems. Cosolvent blending is a low-cost and easy-to-adapt technology that reduces viscosity (and gel point) by diluting the vegetable oil with a low-(molecular weight solvent).” <ref>{{cite journal|last= Dunn|first=R. O.,|title= Low-temperature flow properties of vegetable oil/cosolvent blend diesel fuels.
 
  
−
==The common method of Blending Biofuels Diesel==
+
"Vegetable oils are an attractive renewable source for alternative diesel fuels. However, the relatively high kinematic viscosity of vegetable oils must be reduced to make them more compatible with conventional compression-ignition engines and fuel systems. Cosolvent blending is a low-cost and easy-to-adapt technology that reduces viscosity (and gel point) by diluting the vegetable oil with a low-(molecular weight solvent)." <ref>{{cite journal|last= Dunn|first=R. O.,|title= Low-temperature flow properties of vegetable oil/cosolvent blend diesel fuels.
−
The most common method of blending is to blend a petroleum distillate with a vegetable oil to thin it out to near the viscosity of diesel fuel.  The most common petroleum distillates used in blending are gasoline (petrol), kerosene (paraffin) and/or diesel fuel.  Note: kerosene (paraffin) is not a street-legal fuel in some nations, so there might be heavy fines resulting in their use.
 
  
−
===Other commonly used solvents===
+
==The common method of blending==
−
Other solvents successfully used in making blended biofuels for diesel engines are: Acetone, Methyl Ethel Ketone [http://www.youtube.com/watch?v=crlwFwCvNOQ (MEK)], Pure Gum Turpentine (PGT), Xylene, Toluene, [http://www.youtube.com/watch?v=xAI821bk-zg lacquer thinner], citrus oils, mineral spirits, paint thinner.  Note: some of these solvents are not street-legal, so there might be heavy fines resulting in their use.  They may also be hard on hoses and seals.
 
  
−
===Theory behind Blending Biofuels Diesel===
+
A petroleum distillate is blended with a vegetable oil to thin it out to near the viscosity of diesel fuel. The most common petroleum distillates used in blending are gasoline (petrol), kerosene (paraffin) and/or diesel fuel.
−
A solvent is used to reduce the viscosity of the source oil, because the viscosity of vegetable oils varies from plant oil to plant oil; however, the average is about 12 times as viscous as diesel fuel. Viscosity is also a function of temperature, thus blend ratio is also a function of operating temperature.
 
  
−
===Commonly used solvents in Blending Biofuels Diesel===
+
Note: kerosene is not a street-legal fuel in some countries, so there might be heavy fines resulting from its use.  In the UK no solvent should be used that has not been subject to fuel duty.
−
Since the viscosity of diesel fuel is twice that of gasoline (petrol), then one needs to use twice as much diesel fuel as gasoline (petrol) for the same thinning effect.  And, the viscosity of kerosene (paraffin) is halfway between that of diesel fuel and gasoline (petrol), so half again as much kerosene (paraffin) is needed as gasoline (petrol) to produce a functional vegetable oil-based road fuel for diesel engines.
 
  
−
There are other factors in choosing a solvent for blending.  The most common other factor is the gel-point of the resulting solution. The gel-point of oils and solvents is the point at which a substance begins to solidify.
+
===Other solvents===
  
−
==Low Temperature Gelling==
+
Solvents successfully used in making blends for diesel engines are:
−
There are other factors in choosing a solvent for blending.  The most common other factor is the gel-point of the resulting solution. The gel-point of biodiesel, oils and solvents is the point at which a substance begins to solidify. When these substances are cooled below the gel-point, some of the molecules in these substances begin to aggregate and form crystals, which can plug a fuel filter. There are a number of commercially available additives that will significantly lower the pour point and cold filter plugging point of biodiesel and waste oils. Winter operation is also possible by blending these substabces with other fuel oils including #2 low sulfur diesel fuel and #1 diesel / kerosene or even gasoline (petrol).
 
  
−
===Gel-point of Blended Biofuels Diesel===
+
*Acetone
−
Vegetable oils tend to gel at about 32F (0c). 
+
*Methyl Ethel Ketone [http://www.youtube.com/watch?v=crlwFwCvNOQ (MEK)]
 +
*Pure Gum Turpentine (PGT)
 +
*Xylene
 +
*Toluene [http://www.youtube.com/watch?v=xAI821bk-zg lacquer thinner]
 +
*Citrus oils
 +
*Mineral spirits
 +
*Paint thinners
  
−
Diesel fuel gels at about -22F (-30c).   
+
Note: as above, some of these solvents are not street-legal, depending on your location, so there might be heavy fines resulting in their use.  They may also have detrimental effects on hoses and seals.
  
−
Kerosene (paraffin) gels at about -60F (-51c).
+
===Theory behind blending===
  
−
And, gasoline (petrol) gels at about -131F (-90c).
+
The viscosity of vegetable oils varies from plant oil to plant oil; however, the average is about 12 times as viscous as diesel fuel. Viscosity is also a function of temperature, thus blend ratio is also a function of operating temperature.
  
−
However, a blend gels at a point between the gel points of its components, and is a function of the volumetric relationship between those components.
+
===Solvent ratios===
  
−
===The typical functional blend ratios and useful temperature ranges===
+
Since the viscosity of diesel fuel is twice that of gasoline, then twice as much diesel fuel then gasoline would be required for the same thinning effect.  The viscosity of kerosene (paraffin) is halfway between that of diesel fuel and gasoline.
  
−
50% diesel fuel to 50% vegetable oil will run fine in a heated fuel line up to 212F (100c), and down to 28F (-2c) operating temperature.
+
==Low Temperature Gelling==
  
−
30% kerosene (paraffin) to 70% vegetable oil will run fine in a heated fuel line up to 212F (100c), and down to 15F (-10c)operating temperature.
+
The gel-point of biodiesel, oils and solvents is the point at which a substance begins to solidify. When these substances are cooled below the gel-point, some of the molecules in these substances begin to aggregate and form crystals, which can plug a fuel filter. There are a number of commercially available additives that will significantly lower the pour point and cold filter plugging point of biodiesel and waste oils. Winter operation is also possible by blending these substances with other fuel oils including #2 low sulfur diesel fuel and #1 diesel / kerosene, and even gasoline.
  
−
20% gasoline (petrol) to 80% vegetable oil will run fine in a heated fuel line up to 120F (50c) and down to 0F (-18c)operating temperature.
+
===Gel-point of blends===
  
−
===Blends of more than one solvent can be used===
+
*Vegetable oils tend to gel at about 32F (0C)
−
Some people prefer blending diesel fuel, vegetable oil and gasoline (petrol).  Here are some functional relationships between the three components:
+
*Diesel fuel gels at about -22F (-30C)
 +
*Kerosene (paraffin) gels at about -60F (-51C)
 +
*Gasoline (petrol) gels at about -131F (-90C)
  
−
5% gasoline (petrol), to 40% diesel fuel, to 55% vegetable oil.
+
However, a blend gels at a point between the gel points of its components, and is a function of the volumetric relationship between those components.
  
−
10% gasoline (petrol), to 30% diesel fuel, to 60% vegetable oil.
+
===The typical blend ratios and temperature ranges===
  
−
15% gasoline (petrol), to 20% diesel fuel, to 65% vegetable oil.
+
{|class="wikitable"
 +
|-
 +
!Blend
 +
!Upper temp - heated fuel line
 +
!Lower temp - ambient conditions
 +
|-
 +
|50% diesel fuel to 50% vegetable oil
 +
|212F (100C)
 +
|28F (-2C)
 +
|-
 +
|30% kerosene (paraffin) to 70% vegetable oil
 +
|212F (100C)
 +
|15F (-10C)
 +
|-
 +
|20% gasoline (petrol) to 80% vegetable oil
 +
|120F (50C)
 +
|0F (-18C)
 +
|}
  
−
20% gasoline (petrol), to 10% diesel fuel, to 70% vegetable oil.
+
===Blends of more than one solvent===
  
−
25% gasoline (petrol), to 0% diesel fuel, to 75% vegetable oil.
+
Some people prefer blending diesel fuel, vegetable oil and gasoline.  Here are some practical ratios:
 +
 
 +
{|class="wikitable"
 +
|-
 +
!Gasoline (petrol)
 +
!Diesel
 +
!Vegetable oil
 +
|-
 +
|5%
 +
|40%
 +
|55%
 +
|-
 +
|10%
 +
|30%
 +
|60%
 +
|-
 +
|15%
 +
|20%
 +
|65%
 +
|-
 +
|20%
 +
|10%
 +
|70%
 +
|-
 +
|25%
 +
|0%
 +
|75%
 +
|}
  
 
===Blends with biodiesel===
 
===Blends with biodiesel===
 +
 
It is also common practice to blend solvents into biodiesel to prevent it from gelling at cold temperatures.
 
It is also common practice to blend solvents into biodiesel to prevent it from gelling at cold temperatures.
  
−
Gasoline (petrol), to Biodiesel blend ratios:
+
{|class="wikitable"
−
 
+
|-
−
5% gasoline (petrol), to 95% biodiesel 28F (-2c) operating temperature.
+
!Gasoline (petrol)
−
 
+
!Biodiesel
−
10% gasoline (petrol), to 90% biodiesel 20F (-7c) operating temperature.
+
!Lower operation point
−
 
+
|-
−
15% gasoline (petrol), to 85% biodiesel 10F (-12c) operating temperature.
+
|5%
 +
|95%
 +
|28F (-2c)
 +
|-
 +
|10%
 +
|90%
 +
|20F (-7c)
 +
|-
 +
|15%
 +
|85%
 +
|10F (-12c)
 +
|-
 +
|20%
 +
|80%
 +
|0F (-18c)
 +
|-
 +
|25%
 +
|75%
 +
| -10F (-23c)
 +
|}
  
−
20% gasoline (petrol), to 80% biodiesel 0F (-18c) operating temperature.
+
Note: not all biodiesel gels at the same temperature, so biodiesel made from high melting point esters (HMPE) may require higher levels of gasoline (petrol) added to it to prevent gelling.
  
−
25% gasoline (petrol), to 75% biodiesel -10F (-23c) operating temperature.
+
==Blending Method==
  
−
Note: not all biodiesel gels at the same temperature, so biodiesel made from high melting point esters (HMPE) amy require higher levels of gasoline (petrol) added to it to prevent gelling.
+
Blending methods vary; however, the most common method is to blend the solvent with the source vegetable oil prior to settling, de-watering and filtering, because blending solvents with vegetable oils has three basic functions.  Blending reduces the viscosity of the source oil, reduces its gel-point, and tends to force water and other contaminants out of solution.  Thinned oil will drop its contaminant load much more quickly than the more viscous source oil.  While Straight Vegetable Oil users may settle their oil for weeks, blenders find they can settle their blend for as little as a few hours to a few days.
  
−
==The Blending Method==
+
Thinned vegetable oils will also pass through a filter more quickly than the source oil.  Where Straight Vegetable Oil users may gravity feed their SVO through a filter taking days, thinned vegetable oils will pass through a filter in minutes.
−
 
 
−
Blending methods vary; however, the most common method of making Blended Biofuels Diesel (BBD) is to blend the solvent with the source vegetable oil prior to settling, de-watering and filtering, because blending solvents with vegetable oils has three basic functions.  Blending reduces the viscosity of the source oil, reduces its gel-point, and tends to force water, and other contaminants, out of solution.  This means that thinned oil will drop its contaminant load much more quickly than the more viscous source oil.  Where it is common for Straight Vegetable Oil users will settle their oil for weeks, blenders find they can settle their blend for as little as a few hours to a few days.
 
−
 
 
−
Thinned vegetable oils will also pass through a filter more quickly than the more viscous source oil.  Where Straight Vegetable Oil users may gravity feed their SVO through a filter taking days, thinned vegetable oils will pass through a filter in minutes.
 
  
 
Blended oils will also remain liquid at lower temperatures, so that filtering can take place at much colder temperatures than the source oil will allow.
 
Blended oils will also remain liquid at lower temperatures, so that filtering can take place at much colder temperatures than the source oil will allow.
  
−
A solvent that is readily soluble in vegetable oils, such as petroleum distillates, do not require a great deal of agitation to dissolve into the source vegetable oil, and will remain in solution indefinitely.  Thus, most blenders fill a settling drum to about 75% full with the source oil, then pour on top of that oil their solvent, such as gasoline (petrol), then rock the drum a little, or swirl a paddle a few times around in the solution.
+
A solvent that is readily soluble in vegetable oils, such as petroleum distillates, do not require a great deal of agitation to dissolve into the source vegetable oil, and will remain in solution indefinitely.  Most blenders fill a settling drum to about 75% full with the source oil, then pour on top of that oil their solvent, such as gasoline (petrol), then rock the drum a little, or swirl a paddle a few times around in the solution.
  
 
===Settling===
 
===Settling===
−
Settling Blended Biofuels Diesel (BBD) prior to filtering is simply allowing the blend to remain undisturbed in its settling drum for anywhere from 3 hours to 3 days.
 
  
−
After an adequate settling period most blenders will drain off the precipitates that settle to the bottom of the settling drum.  To facilitate drain off the precipitates blenders will tend to have a cone-shaped, or bell-shaped bottom on their settling drum, and will have a valve at the bottom for draining off those precipitates.
+
Settling prior to filtering is simply allowing the blend to remain undisturbed for anywhere from 3 hours to 3 days.
 +
 
 +
After an adequate settling period most blenders will drain off the precipitates that settle to the bottom of the settling drum.  To facilitate this use a cone-shaped drum (or drum with bell-shaped bottom) with a valve at the bottom for draining off those precipitates.
  
 
===Precipitates ===
 
===Precipitates ===
−
The precipitates that settle out from a blend will begin to settle out within minutes after agitation ceases.  Those precipitates are primarily particulates and liquids.  The particulates precipitates are mostly particles of dust, free-carbon and food particles. The liquid precipitate is mostly water, but there can also be animal fat and lacquers. The water precipitate can contain dissolved components which are common in the commercial kitchen, such as: salt, sugar and spices. Animal fat is problematic because of its high melting point. Lacquer is naturally occurring in vegetable oils.
+
 
 +
Precipitates will begin to settle out within minutes after agitation ceases, and consist of primarily particulates and liquids.  Particulates are dust, free-carbon and food. The liquid precipitate is mostly water, but there can also be animal fat and lacquers. The water precipitate can contain dissolved components which are common in the commercial kitchen, such as salt, sugar and spices. Animal fat is problematic because of its high melting point. Lacquer is naturally occurring in vegetable oils.
  
 
=== Filters and Filtering===
 
=== Filters and Filtering===
−
Cartridge and bag filters that are deigned for filtering drinking water are commonly used for filtering Blended Biofuels Diesel (BBD).  They are very effective for filtering these fuel blend; however, one must keep in mind that some nations blend alcohol at various percentages into gasoline (petrol) fuel stocks. The alcohol content in gasoline (petrol) can cause deterioration of fuel hoses, seals and filter seals, so if one blends with gasoline (petrol), then one should be aware of the alcohol content in this fuel.  Or, filter with bag filters which are not affected by alcohol content in the fluid stream being filtered.
 
  
 +
Cartridge and bag filters that are designed for filtering drinking water are fine for filtering blends.  However, keep in mind that alcohol may be present in small quantities in gasoline fuel stocks. The alcohol content can cause deterioration of fuel hoses, seals and filter seals in the filter system.  Alternatively, filter with bag filters which are not affected by alcohol content.
  
−
==See also==
+
==External links==
−
*Bioliquids  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*EcoJet concept car  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Food, Conservation, and Energy Act of 2008  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Food vs fuel  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Gasoline gallon equivalent  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Greasestock  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Sustainable biofuel  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Table of biofuel crop yields  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*The Big Green Bus  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Tonne of oil equivalent  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Vegetable oil economy  <span style="color:#A9A9A9">(Link to be added)</span>
 
−
*Vegetable oil fuel  <span style="color:#A9A9A9">(Link to be added)</span>
 
  
−
==External links==
 
 
* [http://www.oliomap.com/ Oliomap.com] - Global VegOil / Biodiesel car-conversion and fuel source network map
 
* [http://www.oliomap.com/ Oliomap.com] - Global VegOil / Biodiesel car-conversion and fuel source network map
 
* [http://www.fillup4free.com/ Fill Up 4 Free] - Online community of WVO enthusiasts & map of people with oil to share
 
* [http://www.fillup4free.com/ Fill Up 4 Free] - Online community of WVO enthusiasts & map of people with oil to share
Line 140: Line 190:
 
* [http://www.unep.fr/scp/rpanel/pdf/Assessing_Biofuels_Full_Report.pdf Towards Sustainable Production and Use of Resources: Assessing Biofuels] by the United Nations Environment Programme, October 2009.
 
* [http://www.unep.fr/scp/rpanel/pdf/Assessing_Biofuels_Full_Report.pdf Towards Sustainable Production and Use of Resources: Assessing Biofuels] by the United Nations Environment Programme, October 2009.
 
* [http://www.extension.org/pages/Farm_Energy_Biodiesel_Table_of_Contents Biodiesel Articles on eXtension] -- eXtension (pronounced "E-Extension") is a wiki for extension professors and agents across the United States. The Farm Energy section contains over 30 articles on biodiesel, from the basics to more technical information.
 
* [http://www.extension.org/pages/Farm_Energy_Biodiesel_Table_of_Contents Biodiesel Articles on eXtension] -- eXtension (pronounced "E-Extension") is a wiki for extension professors and agents across the United States. The Farm Energy section contains over 30 articles on biodiesel, from the basics to more technical information.
−
 
 
   
 
   
 
[[User:Jhananda|Jhananda]] 15:42, 20 April 2011 (BST)
 
[[User:Jhananda|Jhananda]] 15:42, 20 April 2011 (BST)
−
 
+
Edited and reformatted by Tony 5 March 2013 (BST)
  
 
[[Category:Blending]]
 
[[Category:Blending]]
 
[[Category:Vegetable oil]]
 
[[Category:Vegetable oil]]

Latest revision as of 01:20, 5 March 2013

Vegetable oil may be blended with solvents as a substitute for petroleum-based diesel fuel. A blend thins the oil to near the viscosity of diesel fuel to improve the burn characteristics and reduce the gel-point. The resulting should be a uniform solution without precipitates.

Error creating thumbnail: Unable to run external programs, proc_open() is disabled. Error code: 1
WVO before solvent is added to it (source: Jeffrey S. Brooks)
Error creating thumbnail: Unable to run external programs, proc_open() is disabled. Error code: 1
WVO as solvent is added to it (source: Jeffrey S. Brooks)
Error creating thumbnail: Unable to run external programs, proc_open() is disabled. Error code: 1
WVO just after solvent is added to it (source: Jeffrey S. Brooks)
Error creating thumbnail: Unable to run external programs, proc_open() is disabled. Error code: 1
WVO five minutes after solvent added to it. The solution has become uniform (source: Jeffrey S. Brooks)

Safety of light solvents in a diesel engine

Blending waste oils with solvents such as gasoline (petrol) or kerosene (paraffin) requires overcoming some myths that persist in the diesel industry. It is commonly believed that they will cause damage to a diesel engine; however, the British owner’s manuals for Mercedes-Benz ref, Mercedes 190D 2.5 Manual ref, BMW Owner's Manual (British) ref and Volkswagen Pickup owner’s manual (equipped with diesel engines from 1978 through 1991) state "UP TO 30% GASOLINE" (or kerosene in the USA) may be added for cold weather starting.

The Haynes Techbook (10330) Diesel Engine Repair Manual also states, "If gasoline is accidentally pumped into the fuel tank, it won't hurt the fuel system or the engine… Gasoline in small amounts – 0 to 30% - isn't noticeable. At higher ratios, the engine will make a knocking noise, which will get louder as the amount of gasoline goes up..."

Research at the University of Wisconsin shows gasoline can be used as a "spark plug" when blended with diesel fuel improves economy and emissions ref

Below 30% in diesel fuel system will not cause mechanical failure, though with higher solvent ratios, hot fuel system components may potentially cause a vapour-lock that prevents the fuel from being pumped.

Cosolvent blending

"Vegetable oils are an attractive renewable source for alternative diesel fuels. However, the relatively high kinematic viscosity of vegetable oils must be reduced to make them more compatible with conventional compression-ignition engines and fuel systems. Cosolvent blending is a low-cost and easy-to-adapt technology that reduces viscosity (and gel point) by diluting the vegetable oil with a low-(molecular weight solvent)." <ref>{{cite journal|last= Dunn|first=R. O.,|title= Low-temperature flow properties of vegetable oil/cosolvent blend diesel fuels.

The common method of blending

A petroleum distillate is blended with a vegetable oil to thin it out to near the viscosity of diesel fuel. The most common petroleum distillates used in blending are gasoline (petrol), kerosene (paraffin) and/or diesel fuel.

Note: kerosene is not a street-legal fuel in some countries, so there might be heavy fines resulting from its use. In the UK no solvent should be used that has not been subject to fuel duty.

Other solvents

Solvents successfully used in making blends for diesel engines are:

  • Acetone
  • Methyl Ethel Ketone (MEK)
  • Pure Gum Turpentine (PGT)
  • Xylene
  • Toluene lacquer thinner
  • Citrus oils
  • Mineral spirits
  • Paint thinners

Note: as above, some of these solvents are not street-legal, depending on your location, so there might be heavy fines resulting in their use. They may also have detrimental effects on hoses and seals.

Theory behind blending

The viscosity of vegetable oils varies from plant oil to plant oil; however, the average is about 12 times as viscous as diesel fuel. Viscosity is also a function of temperature, thus blend ratio is also a function of operating temperature.

Solvent ratios

Since the viscosity of diesel fuel is twice that of gasoline, then twice as much diesel fuel then gasoline would be required for the same thinning effect. The viscosity of kerosene (paraffin) is halfway between that of diesel fuel and gasoline.

Low Temperature Gelling

The gel-point of biodiesel, oils and solvents is the point at which a substance begins to solidify. When these substances are cooled below the gel-point, some of the molecules in these substances begin to aggregate and form crystals, which can plug a fuel filter. There are a number of commercially available additives that will significantly lower the pour point and cold filter plugging point of biodiesel and waste oils. Winter operation is also possible by blending these substances with other fuel oils including #2 low sulfur diesel fuel and #1 diesel / kerosene, and even gasoline.

Gel-point of blends

  • Vegetable oils tend to gel at about 32F (0C)
  • Diesel fuel gels at about -22F (-30C)
  • Kerosene (paraffin) gels at about -60F (-51C)
  • Gasoline (petrol) gels at about -131F (-90C)

However, a blend gels at a point between the gel points of its components, and is a function of the volumetric relationship between those components.

The typical blend ratios and temperature ranges

Blend Upper temp - heated fuel line Lower temp - ambient conditions
50% diesel fuel to 50% vegetable oil 212F (100C) 28F (-2C)
30% kerosene (paraffin) to 70% vegetable oil 212F (100C) 15F (-10C)
20% gasoline (petrol) to 80% vegetable oil 120F (50C) 0F (-18C)

Blends of more than one solvent

Some people prefer blending diesel fuel, vegetable oil and gasoline. Here are some practical ratios:

Gasoline (petrol) Diesel Vegetable oil
5% 40% 55%
10% 30% 60%
15% 20% 65%
20% 10% 70%
25% 0% 75%

Blends with biodiesel

It is also common practice to blend solvents into biodiesel to prevent it from gelling at cold temperatures.

Gasoline (petrol) Biodiesel Lower operation point
5% 95% 28F (-2c)
10% 90% 20F (-7c)
15% 85% 10F (-12c)
20% 80% 0F (-18c)
25% 75% -10F (-23c)

Note: not all biodiesel gels at the same temperature, so biodiesel made from high melting point esters (HMPE) may require higher levels of gasoline (petrol) added to it to prevent gelling.

Blending Method

Blending methods vary; however, the most common method is to blend the solvent with the source vegetable oil prior to settling, de-watering and filtering, because blending solvents with vegetable oils has three basic functions. Blending reduces the viscosity of the source oil, reduces its gel-point, and tends to force water and other contaminants out of solution. Thinned oil will drop its contaminant load much more quickly than the more viscous source oil. While Straight Vegetable Oil users may settle their oil for weeks, blenders find they can settle their blend for as little as a few hours to a few days.

Thinned vegetable oils will also pass through a filter more quickly than the source oil. Where Straight Vegetable Oil users may gravity feed their SVO through a filter taking days, thinned vegetable oils will pass through a filter in minutes.

Blended oils will also remain liquid at lower temperatures, so that filtering can take place at much colder temperatures than the source oil will allow.

A solvent that is readily soluble in vegetable oils, such as petroleum distillates, do not require a great deal of agitation to dissolve into the source vegetable oil, and will remain in solution indefinitely. Most blenders fill a settling drum to about 75% full with the source oil, then pour on top of that oil their solvent, such as gasoline (petrol), then rock the drum a little, or swirl a paddle a few times around in the solution.

Settling

Settling prior to filtering is simply allowing the blend to remain undisturbed for anywhere from 3 hours to 3 days.

After an adequate settling period most blenders will drain off the precipitates that settle to the bottom of the settling drum. To facilitate this use a cone-shaped drum (or drum with bell-shaped bottom) with a valve at the bottom for draining off those precipitates.

Precipitates

Precipitates will begin to settle out within minutes after agitation ceases, and consist of primarily particulates and liquids. Particulates are dust, free-carbon and food. The liquid precipitate is mostly water, but there can also be animal fat and lacquers. The water precipitate can contain dissolved components which are common in the commercial kitchen, such as salt, sugar and spices. Animal fat is problematic because of its high melting point. Lacquer is naturally occurring in vegetable oils.

Filters and Filtering

Cartridge and bag filters that are designed for filtering drinking water are fine for filtering blends. However, keep in mind that alcohol may be present in small quantities in gasoline fuel stocks. The alcohol content can cause deterioration of fuel hoses, seals and filter seals in the filter system. Alternatively, filter with bag filters which are not affected by alcohol content.

External links

Jhananda 15:42, 20 April 2011 (BST) Edited and reformatted by Tony 5 March 2013 (BST)

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